CAMP: Condensed-Phase Photolysis Reaction

Condensed-Phase Photolysis reactions take the form:

\[\ce{ X + h $\nu$ -> Y_1 ( + Y_2 \dots ) }\]

where \(\ce{X}\) is the species being photolyzed, and \(\ce{Y_n}\) are the photolysis products.

The reaction rate can be scaled by providing the "scaling factor" keyword in the json configuration.

Input data for condensed-phase Photolysis reactions have the following format:

{
  "type" : "CONDENSED_PHASE_PHOTOLYSIS",
  "rate" : 123.45,
  "units" : "M",
  "aerosol phase" : "my aqueous phase",
  "aerosol-phase water" : "H2O_aq",
  "reactants" : {
    "spec1" : {},
    ...
  },
  "products" : {
    "spec3" : {},
    "spec4" : { "yield" : 0.65 },
    ...
  },
  "scaling factor": 11.20
}

The key-value pairs reactants, and products are required. Reactants without a qty value are assumed to appear once in the reaction equation. Products without a specified yield are assumed to have a yield of 1.0.

Units for the reactants and products must be specified using the key units and can be either M or mol m-3. If units of M are specified, a key-value pair aerosol-phase water must also be included whose value is a string specifying the name for water in the aerosol phase.

The unit for time is assumed to be s, but inclusion of the optional key-value pair time unit = MIN can be used to indicate a rate with min as the time unit.

The key-value pair aerosol phase is required and must specify the name of the aerosol-phase in which the reaction occurs.